Comparative Study of Crushing Loads of Porous Aluminium- and Copper-Oxides Synthesized Via Space Holding Sintering
DOI:
https://doi.org/10.38032/scse.2026.4.156Keywords:
Metal oxides, Porous materials, Mechanical property, Hardness, Aluminum, CopperAbstract
Because of their many uses in energy storage, environmental remediation, catalysis, and structural materials, porous metal oxides have garnered a lot of interest. In this work, ammonium hydrogen carbonate was used as the space holder in the space holding sintering procedure to create porous copper and aluminium oxides. To create macroporous structures and promote space holder breakdown, the samples were sintered at 750 °C and pressed at 115 MPa. Aluminium oxides showed more porosity than copper oxides for the same amount of space holder content, according to optical microscopy, which confirmed non-uniform pore morphologies. Aluminium oxides produced bigger and more interconnected pores, with pore size distributions ranging from sub-millimeter to several millimetres, according to ImageJ analysis. Porosity rose as space holder content increased, reaching 66.9% for aluminium oxides and 56.7% for copper oxides at 70 weight percent. According to ASTM C365-05 crushing load testing, copper oxides have a higher crushing load than aluminium oxides while having less porosity. These findings support the strong relationship between porosity, pore shape, and mechanical strength and point to a trade-off between structural strength and porous structure in metal oxide foams.
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References
[1] Roger, C., et al., General routes to porous metal oxides via inorganic and organic templates. Journal of Sol-Gel Science and Technology, 1994. 2(1-3): p. 67-72.
[2] Banno, T., et al. Mechanical properties of micro-porous metals produced by space-holding sintering. in Advanced Materials Research. 2007. Trans Tech Publ.
[3] Tiemann, M., Porous metal oxides as gas sensors. Chemistry-A European Journal, 2007. 13(30): p. 8376-8388.
[4] Wang, C., et al., Metal oxide gas sensors: sensitivity and influencing factors. Sensors, 2010. 10(3): p. 2088-2106.
[5] Hendricks, N.R., Porous metal oxide materials through novel fabrication procedures2012: University of Massachusetts Amherst.
[6] Li, B., et al., Synthesis of hierarchically porous metal oxides and Au/TiO2 nanohybrids for photodegradation of organic dye and catalytic reduction of 4-nitrophenol. Journal of Catalysis, 2015. 329(Supplement C): p. 368-378.
[7] Hernández, P.T., S. Hailes, and I. Parkin, Hydrocarbon detection with metal oxide semiconducting gas sensors modified by overlayer or admixture of zeolites Na-A, HY and H-ZSM-5. Sensors and Actuators B: Chemical, 2017. 242: p. 1281-1295.
[8] Li, R., et al., Fabrication of porous SnO 2 nanowires gas sensors with enhanced sensitivity. Sensors and Actuators B: Chemical, 2017.
[9] Wang, Y., et al., Recent advances in ordered meso/macroporous metal oxides for heterogeneous catalysis: a review. Journal of Materials Chemistry A, 2017. 5(19): p. 8825-8846.
[10] Nakajima, H., Fabrication, properties and application of porous metals with directional pores. Progress in Materials Science, 2007. 52(7): p. 1091-1173.
[11] Seuba, J., et al., Mechanical properties and failure behavior of unidirectional porous ceramics. Scientific reports, 2016. 6: p. 24326.
[12] Bridges, D.W., et al., Oxidation of Copper to Cu2 O and CuO (600°–1000° C and 0.026–20.4 atm Oxygen). Journal of the Electrochemical Society, 1956. 103(9): p. 475-478.
[13] Mimura, K., et al., Brief review of oxidation kinetics of copper at 350 C to 1050 C. Metallurgical and Materials Transactions A, 2006. 37(4): p. 1231-1237.
[14] Jeurgens, L., et al., Growth kinetics and mechanisms of aluminum-oxide films formed by thermal oxidation of aluminum. Journal of applied physics, 2002. 92(3): p. 1649-1656.
[15] Prescott, R. and M. Graham, The formation of aluminum oxide scales on high-temperature alloys. Oxidation of metals, 1992. 38(3-4): p. 233-254.
[16] Ruano, O.A., J. Wadsworth, and O.D. Sherby, Deformation of fine-grained alumina by grain boundary sliding accommodated by slip. Acta Materialia, 2003. 51(12): p. 3617-3634.
[17] Sul, Y.T., et al., The electrochemical oxide growth behaviour on titanium in acid and alkaline electrolytes. Medical Engineering and Physics, 2001. 23(5): p. 329-346.
[18] Rahman, M.A., et al., Improvement on electrochemical performances of nanoporous titania as anode of lithium-ion batteries through annealing of pure titanium foils. Journal of Energy Chemistry, 2018. 27(1): p. 250-263.
[19] Ke, Y.-B., B. Cotterell, and Y.-W. Mai, Fracture parameters for sintered steels. Journal of materials science, 1988. 23(8): p. 2965-2970.
[20] Polasik, S., J. Williams, and N. Chawla, Fatigue crack initiation and propagation of binder-treated powder metallurgy steels. Metallurgical and Materials Transactions A, 2002. 33(1): p. 73-81.
[21] Aghion, E. and Y. Perez, Effects of porosity on corrosion resistance of Mg alloy foam produced by powder metallurgy technology. Materials Characterization, 2014. 96: p. 78-83.
[22] Zhao, X., et al., Pore structures of high-porosity NiTi alloys made from elemental powders with NaCl temporary space-holders. Materials Letters, 2009. 63(28): p. 2402-2404.
[23] Amirjan, M. and M. Bozorg, Properties and corrosion behavior of Al based nanocomposite foams produced by the sintering-dissolution process. International Journal of Minerals, Metallurgy, and Materials, 2018. 25(1): p. 94-101.
[24] Standard, A., C365, Standard test method for flatwise compressive properties of sandwich cores, 1994, ASTM C365-94. West Conshohocken, Philadelphia, Pa: ASTM International.
[25] Harris, S.J., et al., Mesopores inside electrode particles can change the Li-ion transport mechanism and diffusion-induced stress. Journal of Materials Research, 2010. 25(08): p. 1433-1440.
[26] Rahman, M.A. and C. Wen, Nanogravel structured NiO/Ni foam as electrode for high-performance lithium-ion batteries. Ionics, 2015. 21(10): p. 2709-2723.
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Copyright (c) 2026 Mohammad Faisal , Mohammod Anwer Jahed , Md. Arafat Rahman, Shaswato Barua , Konok Chandra Bhowmik (Author)

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