Comparative Study of Production of Bio-fuel from Mango Seed Kernel Using Pyrolysis and Chemical Conversion Processes

Authors

  • Md. Mushrafi Al- Mueed Department of Energy Science and Engineering, Khulna University of Engineering & Technology (KUET), Khulna-9203, Bangladesh
  • Md. Masud Rana Department of Chemical Engineering, Khulna University of Engineering & Technology (KUET), Khulna-9203, Bangladesh
  • Md. Hasan Ali Department of Energy Science and Engineering, Khulna University of Engineering & Technology (KUET), Khulna-9203, Bangladesh

DOI:

https://doi.org/10.38032/jea.2025.01.003

Keywords:

Bio-fuel, Mango Seed Kernel, Pyrolysis, Transesterification, Product Yields, Fuel Properties

Abstract

The conversion of mango seed kernel into biofuel was performed through thermal pyrolysis and chemical transesterification process in this present study. The research also involved a comparative analysis of product yield and physico-chemical properties of the resulting biofuel. The pyrolysis experiment was performed in a 22 cm length and 15 cm diameter fixed bed external heating reactor at a temperature ranging from 150 – 350°C using a full-size sample. The major components of the experimental setup included a furnace, fixed-bed external heating reactor, water-cooled condenser, K-type thermocouples, and collectors for liquid and char. Instead of electricity, low-grade waste biomass was used for heating. This process achieved a maximum biofuel yield of 30.18 wt.%. For the chemical process, initially vegetable oil was extracted through a solvent extraction method, mixing the samples in a 1:2 ratio with hexane and stirring the mixture at a temperature between 25 – 50°C for a duration of 3 – 12 hours, resulting in a 17.3 wt.% yield of vegetable oil. After that, the obtained vegetable oil was transesterified using potassium hydroxide as a catalyst at 60°C for 1 – 1.5 hours. A maximum of 75 – 80 wt.% of extracted vegetable oil was converted into biofuel. The produced biofuels were evaluated for their suitability as alternative fuels by analyzing their physico-chemical properties including viscosity, density, pour point, flash point, and gross calorific value.

References

Sundén, B., 2019. Chapter 1 - Introduction and background. In: Hydrogen, batteries and fuel cells. Academic Press, pp.1-13. DOI: https://doi.org/10.1016/B978-0-12-816950-6.00001-4

Madureira, N.L., 2014. Key concepts in energy. In: Oil Reserves and Peak Oil. Springer, Cham, pp.101-130. DOI: https://doi.org/10.1007/978-3-319-04978-6_6

Asaduzzaman, M., Ali, M.H., Pratik, N.A. and Lubaba, N., 2023. Exhaust heat harvesting of automotive engine using thermoelectric generation technology. Energy Conversion and Management: X, 19, p.100398. DOI: https://doi.org/10.1016/j.ecmx.2023.100398

Kader, M., Islam, M., Parveen, M., Haniu, H. and Takai, K., 2013. Pyrolysis decomposition of tamarind seed for alternative fuel. Bioresource Technology, 149, pp.1-7. DOI: https://doi.org/10.1016/j.biortech.2013.09.032

Winch, P. and Stepnitz, R., 2011. Peak oil and health in low-and middle-income countries: impacts and potential responses. American Journal of Public Health, 101(9), pp.1607-1614. DOI: https://doi.org/10.2105/AJPH.2011.300231

Rana, M.M., Al-Mueed, M.M., Islam, M.N. and Ali, M.H., 2025. Production and analysis of biodiesel from mango seed kernels and tamarind seeds using hybrid approach of solvent extraction and transesterification. Results in Engineering, 25, p.103983. DOI: https://doi.org/10.1016/j.rineng.2025.103983

Ali, M.H., Mashud, M., Rubel, M.R. and Ahmad, R.H., 2013. Biodiesel from neem oil as an alternative fuel for diesel engine. Procedia Engineering, 56, pp.625-630. DOI: https://doi.org/10.1016/j.proeng.2013.03.169

Bu, Q., Lei, H., Wang, L., Wei, Y., Zhu, L., Zhang, X., Liu, Y., Yadavalli, G. and Tang, J., 2014. Bio-based phenols and fuel production from catalytic microwave pyrolysis of lignin by activated carbons. Bioresource Technology, 162, pp.142-147. DOI: https://doi.org/10.1016/j.biortech.2014.03.103

Hossain, M.A., Islam, M.R., Ali, M.H. and Mashud, M., 2013. Emission control of DI diesel engine by using aqueous salt solution. International Journal of Scientific & Engineering Research, 4(6). DOI: https://doi.org/10.14299/ijser.2013.06.001

Chen, W.H., Peng, J. and Bi, X.T., 2015. A state-of-the-art review of biomass torrefaction, densification and applications. Renewable and Sustainable Energy Reviews, 44, pp.847-866. DOI: https://doi.org/10.1016/j.rser.2014.12.039

Bullo, T.A. and Fana, F.B., 2021. Production and characterization of biodiesel from avocado peel oils using experimental analysis (ANOVA). Journal of Engineering Advancements, 2(2), pp.104-111. DOI: https://doi.org/10.38032/jea.2021.02.006

Linus, A.A., Mogaji, T.S., Olabanji, O.M. and Ayodeji, O.Z., 2024. Evaluating the fuel potential of castor biodiesel and its blends for land-based gas turbine engine. Journal of Engineering Advancements, 5(4), pp.107-113. DOI: https://doi.org/10.38032/jea.2024.04.002

Demirbas, M.F. and Balat, M., 2006. Recent advances on the production and utilization trends of bio-fuels: a global perspective. Energy Conversion and Management, 47(15-16), pp.2371-2381. DOI: https://doi.org/10.1016/j.enconman.2005.11.014

Alam, M.J., Momin, M.A., Ahmed, A., Rahman, R., Alam, K., Islam, A.J. and Ali, M.M., 2017. Production performance of mango in Dinajpur district of Bangladesh (a case study at Sadar Upazilla). European Journal of Agriculture and Forestry Research, 5, pp.16-57.

Geerkens, C.H., Nagel, A., Just, K.M., Miller-Rostek, P., Kammerer, D.R., Schweiggert, R.M. and Carle, R., 2015. Mango pectin quality as influenced by cultivar, ripeness, peel particle size, blanching, drying, and irradiation. Food Hydrocolloids, 51, pp.241-251. DOI: https://doi.org/10.1016/j.foodhyd.2015.05.022

Hasan, K., 2023. DAE predicts record mango production in FY23. [online] Available at: https://businesspostbd.com/back/2023-05-29/dae-predicts-record-mango-production-in-fy23-2023-05-29 [Accessed 20 March 2025].

Amla, B.L. and Potty, V.H., 1985. Development of energy-saving technologies for food processing. Food and Nutrition Bulletin, 7(2), pp.1-8. DOI: https://doi.org/10.1177/156482658500700211

Alencar, W.S., Acayanka, E., Lima, E.C., Royer, B., Souza, F.E., Lameira, J. and Alves, C.N., 2012. Application of Mangifera indica (mango) seeds as a biosorbent for removal of Victazol Orange 3R dye from aqueous solution and study of the biosorption mechanism. Chemical Engineering Journal, 209, pp.577-588. DOI: https://doi.org/10.1016/j.cej.2012.08.053

Kittiphoom, S., 2012. Utilization of mango seed. International Food Research Journal, 19(4), pp.1325-1335.

Henrique, M.A., Silvério, H.A., Neto, W.P.F. and Pasquini, D., 2013. Valorization of an agro-industrial waste, mango seed, by the extraction and characterization of its cellulose nanocrystals. Journal of Environmental Management, 121, pp.202-209. DOI: https://doi.org/10.1016/j.jenvman.2013.02.054

Perea-Moreno, A.-J., Perea-Moreno, M.-Á., Dorado, M.P. and Manzano-Agugliaro, F., 2018. Mango stone properties as biofuel and its potential for reducing CO2 emissions. Journal of Cleaner Production, 190, pp.53-62. DOI: https://doi.org/10.1016/j.jclepro.2018.04.147

Moyo, M., Pakade, V.E. and Modise, S.J., 2017. Biosorption of lead (II) by chemically modified Mangifera indica seed shells: Adsorbent preparation, characterization and performance assessment. Process Safety and Environmental Protection, 111, pp.40-51. DOI: https://doi.org/10.1016/j.psep.2017.06.007

Demirbas, A., 2009. Potential resources of non-edible oils for biodiesel. Energy Sources, Part B, 4(3), pp.310-314. DOI: https://doi.org/10.1080/15567240701621166

Gui, M., Lee, K. and Bhatia, S., 2008. Feasibility of edible oil vs. non-edible oil vs. waste edible oil as biodiesel feedstock. Energy, 33(11), pp.1646-1653. DOI: https://doi.org/10.1016/j.energy.2008.06.002

Chaiyaa, C. and Reubroycharoenb, P., 2013. Production of bio-oil from para rubber seed using pyrolysis process. Energy Procedia, 34, pp.905-911. DOI: https://doi.org/10.1016/j.egypro.2013.06.828

Duman, G., Okutucu, C., Ucar, S., Stahl, R. and Yanik, J., 2011. The slow and fast pyrolysis of cherry seed. Bioresource Technology, 102(2), pp.1869-1878. DOI: https://doi.org/10.1016/j.biortech.2010.07.051

Shadangi, K.P. and Mohanty, K., 2014. Effect of co-pyrolysis of mahua seed and waste polystyrene on quality of liquid fuel. Journal of Renewable and Sustainable Energy, 6, p.053142. DOI: https://doi.org/10.1063/1.4900550

Larrauri, J., Rupérez, P., Borroto, B. and Saura-Calixto, F., 1996. Mango peels as a new tropical fibre: preparation and characterization. LWT-Food Science and Technology, 29(8), pp.729-733. DOI: https://doi.org/10.1006/fstl.1996.0113

Sultana, B. and Ashraf, R., 2019. Mango (Mangifera indica L.) seed oil. In: Fruit Oils: Chemistry and Functionality. Springer, Cham, pp.561-575. DOI: https://doi.org/10.1007/978-3-030-12473-1_28

Saka, A., Enkosa, E., Jule, L.T., Nagaprasad, N., Subramanian, K. and Ramaswamy, K., 2022. Biofuel production from mango (Mangifera indica) seed extracts through zinc oxide nanoparticle. Biomass Conversion and Biorefinery, pp.1-11. DOI: https://doi.org/10.1007/s13399-022-03005-y

Julio, L.G., Aranguren, D.D. and Sierra, R., 2021. Biodiesel synthesis from mango (Mangifera indica) seed oil extracted with supercritical carbon dioxide. In: 29th European Biomass Conference and Exhibition.

Narayanasamy, G., Padmesh, T. and Krishnan, S., 2022. Experimental studies on transesterification of mango (Mangifera indica) seed kernel butter for biodiesel production. IOP Conference Series: Materials Science and Engineering, 1257(1), p.012012. DOI: https://doi.org/10.1088/1757-899X/1257/1/012012

Ganeshan, G., Shadangi, K.P. and Mohanty, K., 2016. Thermo-chemical conversion of mango seed kernel and shell to value-added products. Journal of Analytical and Applied Pyrolysis, 121, pp.403-408. DOI: https://doi.org/10.1016/j.jaap.2016.09.004

Lam, S.S., Liew, R.K., Lim, X.Y., Ani, F.N. and Jusoh, A., 2016. Fruit waste as feedstock for recovery by pyrolysis technique. International Biodeterioration & Biodegradation, 113, pp.325-333. DOI: https://doi.org/10.1016/j.ibiod.2016.02.021

Lazzari, E., Schena, T., Primaz, C.T., Maciel, G.P., Machado, M.E., Cardoso, C.A.L., Jacques, R.A. and Caramão, E.B., 2016. Production and chromatographic characterization of bio-oil from the pyrolysis of mango seed waste. Industrial Crops and Products, 83, pp.529-536. DOI: https://doi.org/10.1016/j.indcrop.2015.12.073

Andrade, L.A., Barrozo, M.A.S. and Vieira, L.G.M., 2016. Thermo-chemical behavior and product formation during pyrolysis of mango seed shell. Industrial Crops and Products, 85, pp.174-180. DOI: https://doi.org/10.1016/j.indcrop.2016.03.004

Ali, M.H. and Moral, M.N.A., 2022. Pyrolytic fuel extraction from tire and tube: Analysis of parameters on product yield. Case Studies in Chemical and Environmental Engineering, 6, p.100273. DOI: https://doi.org/10.1016/j.cscee.2022.100273

Mohammad, I., Abakr, Y., Kabir, F., Yusuf, S., Alshareef, I. and Chin, S., 2015. Pyrolysis of Napier grass in a fixed bed reactor: effect of operating conditions on product yields and characteristics. BioResources, 10(4), pp.6457-6478. DOI: https://doi.org/10.15376/biores.10.4.6457-6478

Dyjakon, A., Sobol, Ł., Noszczyk, T. and Mitręga, J., 2022. The impact of torrefaction temperature on the physical-chemical properties of residual exotic fruit (Avocado, Mango, Lychee) seeds. Energies, 15(2), p.612. DOI: https://doi.org/10.3390/en15020612

Zhang, X., Peterson, C., Reece, D., Haws, R. and Möller, G., 1998. Biodegradability of biodiesel in the aquatic environment. Transactions of the ASAE, 41(5), pp.1423-1430. DOI: https://doi.org/10.13031/2013.17277

Yaman, S., 2004. Pyrolysis of biomass to produce fuels and chemical feedstocks. Energy Conversion and Management, 45(5), pp.651-671. DOI: https://doi.org/10.1016/S0196-8904(03)00177-8

Pütün, A.E., Apaydın, E. and Pütün, E., 2004. Rice straw as a bio-oil source via pyrolysis and steam pyrolysis. Energy, 29(12-15), pp.2171-2180. DOI: https://doi.org/10.1016/j.energy.2004.03.020

Mashud, M., Ali, M.H., Roknuzzaman, M. and Galib, A.A., 2009. Biodiesel from jatropha oil as an alternative fuel for diesel engine. Proceedings of the International Conference on Mechanical Engineering, Dhaka, Bangladesh.

Venkatachalam, C.D., Sengottian, M., Sivasamy, K.S., Rajadurai, G. and Mani, G., 2020, May. Production of biodiesel from waste cooking oil under varying parametric conditions using hydrodynamic cavitation with a single holed orifice. In AIP Conference Proceedings (Vol. 2240, No. 1). AIP Publishing. DOI: https://doi.org/10.1063/5.0011000

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Published

29-03-2025

How to Cite

Al- Mueed, M. M. ., Rana, M. M. ., & Ali, M. H. (2025). Comparative Study of Production of Bio-fuel from Mango Seed Kernel Using Pyrolysis and Chemical Conversion Processes. Journal of Engineering Advancements, 6(01), 16–21. https://doi.org/10.38032/jea.2025.01.003
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