Novel Biosorption Method for Eliminating Methylene Blue Dye from Wastewater Using Sweet Potato Peels

Authors

  • Ali Husnain Muhammad Nawaz Sharif University of Engineering & Technology image/svg+xml
    • Methodology
    • Investigation
    • Data Curation
    • Formal Analysis
    • Writing – Review & Editing
  • Amna Azam Muhammad Nawaz Sharif University of Engineering & Technology image/svg+xml
    • Conceptualization
    • Formal Analysis
    • Writing – Review & Editing
  • Asim Umer
    • Supervision

DOI:

https://doi.org/10.38032/jea.2025.03.002

Keywords:

Biosorption, Sweet potato peel, Methylene blue, Wastewater treatment, Adsorption kinetics

Abstract

This study explores the use of sweet potato peels, Ipomoea batatas (SPP) as biosorbent for elimination of Methylene Blue, Methylthioninium chloride (MB) dye from aqueous solutions. Batch adsorption experiments were performed to evaluate the effects of key variables, including adsorbent dosage, contact time, and initial dye concentration, on the removal efficiency of MB. The results demonstrated that the removal efficiency of MB increased with the adsorbent dosage, reaching an optimal value of 72% at a dosage of 1.0 g/100 mL, corresponding to a maximum adsorption capacity of 7.2 mg/g. Additionally, the adsorption process achieved equilibrium at 50 minutes of contact time. However, higher concentrations of MB in the solution led to a decrease in removal efficiency, likely due to the saturation of the adsorbent surface. Further analysis using FTIR spectroscopy revealed the presence of functional groups such as hydroxyl, carboxyl, and phenolic groups on the sweet potato peel surface, which play a crucial role in the adsorption process. Kinetic modeling using the pseudo-second-order model revealed that the pseudo-second-order model provided the best fit with R² > 0.99, confirming chemisorption behavior. The study concluded that sweet potato peels are an effective, eco-friendly adsorbent for MB dye removal, demonstrating a low-cost and sustainable approach to wastewater treatment. The findings highlight the potential of this agricultural byproduct in addressing water pollution concerns, providing a viable solution aligned with environmental conservation efforts.

References

[1] Dominguez, M., Mendoza, J. and Figueroa, K., 2024. Adsorption of methylene blue dye using common walnut shell (Juglans regia) like biosorbent: Implications for wastewater treatment. Green Chemistry Letters and Reviews, 17(1), p.2362257. DOI: https://doi.org/10.1080/17518253.2024.2362257

[2] Aniagor, C.O., Aly, A.A., Mohamed, L.A. and Hashem, A., 2024. Removal of Methylene blue dye from contaminated wastewater using lignocellulosic biomasses: A comparative study. Waste Management Bulletin, 2(2), pp.213-225. DOI: https://doi.org/10.1016/j.wmb.2024.05.003

[3] Abbas, M., 2022. Removal of methylene blue pollutant from the textile industry by adsorption onto Zeolithe: Kinetic and thermodynamic study. Journal of Engineered Fibers and Fabrics, 17, p.1558925021993692. DOI: https://doi.org/10.1177/1558925021993692

[4] Alam, M.Z., Bari, M.N. and Kawsari, S., 2022. Statistical optimization of Methylene Blue dye removal from a synthetic textile wastewater using indigenous adsorbents. Environmental and Sustainability Indicators, 14, p.100176. DOI: https://doi.org/10.1016/j.indic.2022.100176

[5] Ekinci, S., 2023. Elimination of methylene blue from aqueous medium using an agricultural waste product of crude corn silk (Stylus maydis) and corn silk treated with sulphuric acid. ChemistrySelect, 8(18), p.e202300284. DOI: https://doi.org/10.1002/slct.202300284

[6] El-Bery, H.M., Saleh, M., El-Gendy, R.A., Saleh, M.R. and Thabet, S.M., 2022. High adsorption capacity of phenol and methylene blue using activated carbon derived from lignocellulosic agriculture wastes. Scientific reports, 12(1), p.5499. DOI: https://doi.org/10.1038/s41598-022-09475-4

[7] Abouzeid, R., Sadeghi, P., Picha, D.H. and Wu, Q., 2025. Sustainable nanocoatings for agricultural produce: A biodegradable approach using cellulose nanomaterials and pectin from sweet potato peel. Carbohydrate Polymer Technologies and Applications, 10, p.100785. DOI: https://doi.org/10.1016/j.carpta.2025.100785

[8] Hamad, H.N. and Idrus, S., 2022. Recent developments in the application of bio-waste-derived adsorbents for the removal of methylene blue from wastewater: a review. Polymers, 14(4), p.783. DOI: https://doi.org/10.3390/polym14040783

[9] Hambisa, A.A., Regasa, M.B., Ejigu, H.G. and Senbeto, C.B., 2023. Adsorption studies of methyl orange dye removal from aqueous solution using Anchote peel-based agricultural waste adsorbent. Applied Water Science, 13(1), p.24. DOI: https://doi.org/10.1007/s13201-022-01832-y

[10] Holliday, M.C., Parsons, D.R. and Zein, S.H., 2024. Agricultural pea waste as a low-cost pollutant biosorbent for methylene blue removal: adsorption kinetics, isotherm and thermodynamic studies. Biomass Conversion and Biorefinery, 14(5), pp.6671-6685. DOI: https://doi.org/10.1007/s13399-022-02865-8

[11] Kausar, A., Rehman, S.U., Khalid, F., Bonilla-Petriciolet, A., Mendoza-Castillo, D.I., Bhatti, H.N., Ibrahim, S.M. and Iqbal, M., 2022. Cellulose, clay and sodium alginate composites for the removal of methylene blue dye: Experimental and DFT studies. International journal of biological macromolecules, 209, pp.576-585. DOI: https://doi.org/10.1016/j.ijbiomac.2022.04.044

[12] Kavci, E., Erkmen, J. and Bingöl, M.S., 2023. Removal of methylene blue dye from aqueous solution using citric acid modified apricot stone. Chemical Engineering Communications, 210(2), pp.165-180. DOI: https://doi.org/10.1080/00986445.2021.2009812

[13] Mekuria, D., Diro, A., Melak, F. and Asere, T.G., 2022. Adsorptive removal of methylene blue dye using biowaste materials: barley bran and enset midrib leaf. Journal of Chemistry, 2022(1), p.4849758. DOI: https://doi.org/10.1155/2022/4849758

[14] Mphuthi, B.R., Thabede, P.M., Monapathi, M.E. and Shooto, N.D., 2023. Hemp seed nanoparticle composites for removing lead, methylene blue, and ibuprofen from an aqueous solution and their antimicrobial towards Escherichia coli and Staphylococcus aureus. Case Studies in Chemical and Environmental Engineering, 8, p.100436. DOI: https://doi.org/10.1016/j.cscee.2023.100436

[15] Ofgea, N.M., Tura, A.M. and Fanta, G.M., 2022. Activated carbon from H3PO4-activated Moringa Stenopetale Seed Husk for removal of methylene blue: Optimization using the response surface method (RSM). Environmental and Sustainability Indicators, 16, p.100214. DOI: https://doi.org/10.1016/j.indic.2022.100214

[16] Oladoye, P.O., Ajiboye, T.O., Omotola, E.O. and Oyewola, O.J., 2022. Methylene blue dye: Toxicity and potential elimination technology from wastewater. Results in Engineering, 16, p.100678. DOI: https://doi.org/10.1016/j.rineng.2022.100678

[17] El Naeem, G.A., Abd-Elhamid, A.I., Farahat, O.O., El-Bardan, A.A., Soliman, H.M. and Nayl, A.A., 2022. Adsorption of crystal violet and methylene blue dyes using a cellulose-based adsorbent from sugercane bagasse: characterization, kinetic and isotherm studies. Journal of Materials Research and Technology, 19, pp.3241-3254. DOI: https://doi.org/10.1016/j.jmrt.2022.06.045

[18] Zhu, H., Chen, S. and Luo, Y., 2023. Adsorption mechanisms of hydrogels for heavy metal and organic dyes removal: A short review. Journal of Agriculture and Food Research, 12, p.100552. DOI: https://doi.org/10.1016/j.jafr.2023.100552

[19] Sah, M.K., Edbey, K., EL-Hashani, A., Almshety, S., Mauro, L., Alomar, T.S., AlMasoud, N. and Bhattarai, A., 2022. Exploring the biosorption of methylene blue dye onto agricultural products: A critical review. Separations, 9(9), p.256. DOI: https://doi.org/10.3390/separations9090256

[20] Sawalha, H., Bader, A., Sarsour, J., Al-Jabari, M. and Rene, E.R., 2022. Removal of dye (methylene blue) from wastewater using bio-char derived from agricultural residues in palestine: Performance and isotherm analysis. Processes, 10(10), p.2039. DOI: https://doi.org/10.3390/pr10102039

[21] Xue, H., Wang, X., Xu, Q., Dhaouadi, F., Sellaoui, L., Seliem, M.K., Lamine, A.B., Belmabrouk, H., Bajahzar, A., Bonilla-Petriciolet, A. and Li, Z., 2022. Adsorption of methylene blue from aqueous solution on activated carbons and composite prepared from an agricultural waste biomass: A comparative study by experimental and advanced modeling analysis. Chemical engineering journal, 430, p.132801. DOI: https://doi.org/10.1016/j.cej.2021.132801

[22] Yadav, S.K., Dhakate, S.R. and Singh, B.P., 2022. Carbon nanotube incorporated eucalyptus derived activated carbon-based novel adsorbent for efficient removal of methylene blue and eosin yellow dyes. Bioresource Technology, 344, p.126231. DOI: https://doi.org/10.1016/j.biortech.2021.126231

[23] Wang, K., Ding, J., Shi, J., Deng, J. and Huang, H., 2024. Multi-Scale characteristics of coal secondary spontaneous combustion under different Pre-Heating oxygen concentrations by TG and FTIR analysis. Combustion Science and Technology, 196(18), pp.4982-4997. DOI: https://doi.org/10.1080/00102202.2023.2248367

[24] Bourahla, S., Nemchi, F., Belayachi, H., Belayachi, A., Harrats, C. and Belhakem, M., 2023. Removal of the AO7 dye by adsorption on activated carbon based on grape marc: Equilibrium, regeneration, and FTIR spectroscopy. Journal of the Iranian Chemical Society, 20(3), pp.669-681. DOI: https://doi.org/10.1007/s13738-022-02705-6

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Published

04-09-2025

Data Availability Statement

Data will be made available on request.

Issue

Section

Research Articles

How to Cite

Husnain, A., Azam, A. and Umer, A. (2025) “Novel Biosorption Method for Eliminating Methylene Blue Dye from Wastewater Using Sweet Potato Peels”, Journal of Engineering Advancements, 6(03), pp. 86–93. doi:10.38032/jea.2025.03.002.